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MI is the company, that offers the first commercially available continuous emission monitor (CEM) for stack gases, the Stack Monitor SM-3, with a new operating principle, based on the thermo-catalytic method. Wet chemical sample gas treatment using reagents and bubblers is avoided! The SM-3 is approved by German TÜV.

 
View Manualcoming soon   View Manual
 
Fields of application

The SM-3 Mercury Stack Gas Monitor is used for continuous monitoring of mercury in stack gas. Bound forms of mercury like HgCl2, HgO, HgS and particulate mercury are detected as well as elemental mercury.

  • Municipal Waste Incinerators
  • Sewage Sludge Incinerators
  • Hazardous Waste Incinerators
  • Cement Production
  • Coal Fired Power Plants
  • Thermal Soil Resanitation Plants
  • Wood Combustors Using Recycled Wood
  • Metal Recycling Furnaces

Operating principle

A sample gas stream is taken from the duct through a heated sampling system. The gas is drawn through a high-temperature particulate filter and subsequently enters the reduction unit. In this part of the analyzer a thermo-catalytic reduction of ionic and bound mercury is performed. Elemental mercury vapor is formed as a result of this transformation process. The gas is then dried in a maintenance-free peltier cooler and fed to the mercury detector where the mercury concentration is measured with the so called "cold vapor atomic absorption spectroscopy (CVAAS)" method. The high surface temperature of the gas entry filter guarantees that mercury is thermally completely desorbed from particles and thus also detected.

 

 

 

 

Design features

All surfaces coming into contact with the sample gas are heated to temperatures >180¡C to prevent any adsorptional loss of mercury . The sample line is made of perfluoralkoxy (PFA), a material which shows extremely weak interaction with mercury vapor. Sampling and reduction are performed at temperatures far above the dew point. Therefore no condensate is formed before all mercury is in elemental state. This minimizes signal noise and avoids nonspecific peaks.

The SM-3 avoids to use any gold collector for mercury preconcentration thus giving a very fast response and providing results continuously and in real-time. Possible problems connected with "poisoning" of the gold surface are thus eliminated.

The straightforward analysis avoiding wet-chemical sample treatment and avoiding a gold trap ensures high reliability and low maintenance.

 

Easy to operate
The SM-3 is operated via a waterproof membrane keypad. All inputs required are selected in a readily understandable menu shown on the graphical display. It is also possible to initiate functions like zero adjustment and calibration check from an external computer.

Low maintenance and low costs of ownership
Thanks to the new thermo-catalytic sample treatment method no reagents are required. Compared to first generation instruments employing wet chemical sample preparation methods, the SM-3 features clearly increased reliability and requires only minimum maintenance. This results in particularly low cost of ownership and maximum availability.

UV-Photometer
Quantitative determination of the mercury concentration is performed in a UV-photometer with an electrodeless low-pressure mercury lamp. This lamp is controlled using the reference-beam-method which ensures a highly stable baseline.
 

Automatic zero adjustment
The zero line of the SM-3 is checked and adjusted automatically after a preset period of time. A magnetic valve stops the sample gas stream and switches over to zero air which has been cleaned in a carbon filter. Automatic zero adjustment is performed every hour and requires 30 seconds.

Automatic self-cleaning filter
To prevent the instrument from being plugged up by dust-particles, the SM-3 has a self-cleaning filter system which is operated by compressed air. The cleaning function is automatically activated every hour and is a matter of seconds

Sampling system
The sample gas is extracted with a stainless steel probe and conducted through a heated tube to the analyzer. The entire sample line is made of perfluoralkoxy (PFA), a material guaranteeing a minimal memory effect. The dimensions of the sampling system mounting flange are customized (for example DN 80/PN 6 or ANSI 3"/ 150 labs).
 

The importance of continuous mercury emission monitoring
Monitoring of mercury emissions from stack has become a global issue. More strict regulations by authorities as well as the public claim for a complete surveillance of incinerators have caused an increasing interest in continuous emission monitors (CEMs) for mercury. For the potential user of such systems it is important to find a reliable and economic solution. First generation CEMs for mercury were based on the automation of known laboratory methods. This resulted in high maintenance costs, unreliable operation, oversized and heavy construction and last but not least a high price.

A new analytical solution: the SM-3

The operating principle of the SM-3 is based on a completely new technique. Cracking and reduction of bound and ionic mercury contained in stack gas is performed applying the thermo-catalytic method. Wet chemical sample gas treatment using reagents and bubblers is avoided. Maintenance and servicing of the SM-3 are therefore extremely easy. Purchasing costs for purchase and costs of ownership are comparatively low.

As the SM-3 is a compact-sized and low-weight device, it may also be used for mobile applications. Installation is easy and done in a short time.

 


SM-3 Technical Specifications
Measuring component:  total mercury Hg(tot) 
Measuring principle:  UV-Absorption after thermo-catalytic sample gas treatment 
Measuring range:  0 - 45; 0-75; 0-500 µg/m³ (others upon request) 
Detection limit:  < 1% of measuring range 
Response time T90:  < 60 seconds 
Measurement cycle time:  none, continuous measurement without time gaps 
Zero drift:  < 1 % of range, auto zero 
Air supply:  oilless compressed air, approx. 2.0 bar (approx. 25 psi) 
Operating temperature:  5 - 40 °C 
Signal outputs:  4-20 mA (max. load 500 Ohms) 
digital status outputs (relais contacts) 
Power Supply:  230 VAC/ 50-60 Hz (optional 115 VAC / 50-60Hz) 
Power consumption:  max. 1000 VA (analyzer) 
max. 150 VA/m (sample line) 
Dimensions:  550 x 1000 x 700 mm (WxHxD) 
Weight:  approx. 50 kg 
 
                                                                                                         

Hg-CEM Questionnaire for CDFs

1. SETUP

1.1 : What are the space requirements ?

VIEW DIAGRAM

 

1.2 : What are utility requirements?

230 VAC, ca. 750 VA for analyzer, ca. 120 VA per meter for heated sample line

compressed air, oil-free, ca. 10 l/hour

1.3 : What range of ambient conditions can the CEM tolerate?

+ 5°C to + 40 °C

1.4: Are there any other requirements for unit location or setup?

sample line as short as possible, standard length 10-12 m, maximum 20-30 m

2. MERCURY ANALYSIS METHOD

2.1: Mercury speciation or total mercury?

Total mercury

2.2: Is particulate-bound mercury detected? By what method?

Yes, thermal desorption of particulate Hg at ca. 400 °C

2.3: Do false positives occur?

Yes,  if SO2 greater than 100 mg/m³. Can be corrected very exactly if signal/concentration of SO2 is available

Yes, if benzene is > 1 mg/m³

2.4: Would mercury spikes beyond the instrument span overload the CEM and require downtime to reset?

depending on the peak concentration and duration it may take some minutes to some hours until excess Hg is purged out

2.5: What are the cycle times? Please give time for each step.

No cycle time, real continuous measurement

2.6 : Are multiple instrument spans available in the same CEM? Is there automatic switching of spans?

Yes: 3 spans. Manual switching. Automatic as an option.

3. CALIBRATION

3.1: Describe the calibration method.

Calibration is performed by feeding the instrument with humid (! Important!) ionic mercury (Hg-II) calibration gas. We use the "HOVACAL" calibrator which has been approved. Official calibration is performed by comparison of the instrument´s reading with results from manual reference analyses.

Automatic calibration is possible with a permeation device for elemental Hg attached to the analyzer.

3.2: What calibration frequency is recommended?

Calibration check every 6 months is recommended.

3.3: What percentage of time would the CEM be offline for routine calibration?

Manual routine calibration time requirement: ca. 30 min to 1 hour.

3.4: What mercury calibration gases are required?

Cf. 3.1

4. SIGNAL OUTPUT

4.1: What signal outputs (including Hg concentration, CEM operational status, calibration status, etc.) are available?

Measuring signal 4-20 mA, status outputs for "zeroing/calibration", "maintenance", "malfunction"

4.2:What is the form of the signal outputs?

4-20 mA, potential-free relais contacts

 

5. SAMPLE EXTRACTION SYSTEM

5.1: What type of sample extraction system is used?

heated sample line with passive heated probe tip

5.2: What is the maximum recommended sample line length?

up to 30 meters, optimum <12 m

5.3 :What is the sample line material of construction?

PFA tubing, from tip to thermo-catalytic reactor intake fitting

 

5.4: What is the acceptable temperature range for the sampling line?

ambient temp range from –20 °C to + 50 °C

Heating temp 170-190 °C

5.5: What type of filtration is used?

Heated glass filter (400 °C)

5.6 : Would it be possible to analyze gas samples drawn from two different process locations? If so, what would be the switching interval? Would there be difficulties with cross-contamination?

Absolutely not recommended.

6. REGULATORY REQUIREMENT

 

6.2: Is the CEM TUV-certified?

Yes, the SM-3 has been TÜV certified and approved in 1999 as the first instrument working on thermocatalytic principle.

6.3 : Is the CEM MCERTS certified?

Manufacturing according to ISO 9000

 

6.5: Were the interference response tests conducted with individual interference gases or with a mixture of gases?

With individual gases. If other tests have been carried out is not known

7 TESTING

7.2: What independent performance testing has been conducted to date? Please provide results.

More than 40 installations. For each instrument functional tests have been carried out. A variety of other tests (for example comparative tests of instruments from different manufacturers at cement kilns by the German Research Institute of the Cement Industry) have been carried out too.

7.3: What testing is planned for the future?

SM-3 testing and evaluation will be conducted at a proprietary US site from August –October 2002

 

8. OPERATION

8.1: What routine maintenance (type and time is required)?

Discharge of condensate every 4-8 weeks. Routine maintenance every 6 months (requiring ca. 3-4 hours of work). Cleaning tubing + reactor, replacement of peristaltic pump tubing, cleaning of glass filter.

 

8.2: What degree of skill and training is required of the CEM operator? Is training provided onsite?

Averagely skilled personnel who is used to maintain other analyzers. Training can be provided during start-up (1 day). Generally the analyzer is easy to understand and to maintain. No complicated adjustments.

8.3: How much operator time is required?

Operator time: 0.5 … 5 hours/month

8.4: Is there failure rate or availability data for the CEM?

Availability (run time of the analyzer) during standard operation: 95- 100 %. During approval test: one instrument 98,6 %, second instrument 99,2 %)

 

9 GAS CONDITIONS

    1. The following parameters represent the range of gas conditions expected in the streams to be sampled. Please indicate any values which are a potential problem, and any parameters which have not been tested on the CEM.

N2 35-75%

O2 3-10%

CO2 3-10%

H2O 10-55%

CO 0-76 ppmv

NOx 0-350 ppmv

SOx 0-350 ppmv

HCL 0-10 ppmv

CL2 0-10 ppmv

HF 0-10 ppmv

TOC 0-5 ppmv as propane

P2O5 0-5 ppmv

PM 0-300 ppmw

HG° 0-150 ug/m3 (total Hg)

Differential Pressure –55 in w.c.

Relative Humidity 10-50%

Temperature 150-300 F

Degrees Above Saturation 25-125 F

There is no major problem visible, but we don’t know the behavior if all these components are present.

10 REAGENTS AND SECONDARY WASTE

10.1: What types and quantities of chemical reagents and other expendable materials are required?

None used

10.2: What types and quantities of secondary waste are generated by the CEM?

Stack gas condensate. Amount dependent on humidity of sample, ca. 0.2-0.51/d

 

  1. INDUSTRIAL EXPERIENCE AND REFERENCES
    1. List industrial applications to date.

      The SM-3 has been installed at municipal waste incinerators, industrial waste incinerators, sewage sludge incinerators, waste pyrolysis plants, paper industry waste incinerators, coal fired power plants and cement kilns.

    2. WARRANTY AND TECHNICAL SUPPORT
    3. What type of warranty and technical support are provided with the CEMS?

      6 Month Warranty

    4. Is technical support provided in the USA?

      Yes

    5. Are repair service provided in the USA?

      Yes

  2. COST
    1. What are the equipment and estimated installed cost for the CEM?

      $60,000.00

    2. What is the estimated operating cost?

      Minimal

     

     

     

  3. FUTURE DEVELOPMENT
    1. What are the plans for future development of the CEM?

      The SM-4 is under development

    2. Is a new model planned? If so, when?

    The SM-4 will be under testing possibly by the end of 2002.

 

 

 

 

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